You can't on verizon. Comcast allows you to watch past episodes of network and some cable network shows that you have missed. Verizon charges and that is if they are even available on demand.
There is a lot of Free VOD including ABC CBS NBC etc. I am able to watch a lot of stuff.
Not every network show is available with VOD, but that's not necessarily Verizon's fault. Some studios keep their shows off VOD, and some networks hold episodes back for a week or more.
If you can't find your favorite show on VOD, check the network's web site -- you might be able to watch the show on your computer screen.
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